Gyarados
Gyarados's shiny form appeared in late Johto, however it wasn't officially a Shiny form. In it, Team Rocket were forcing evolutions of Magikarp into Gyarados but the Gyarados failed to change Colour during evolution. It got very angry and started a Rampage in the Lake of Rage and Mahogany time. Luckily Lance Captured it and stopped it. He later on used it in Hoenn to help stop Kyogre & Groudon's battle
First Seen: Episode 237: Talkin Bout An Evolution
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