Like the previous game, Pokémon Rumble Blast hallows you to teach your Pokémon a variety of new moves through vending machines. However, unlike in the original, this isn't just through randomisation, but there are various vending machines around Toyland which allow you to teach the Pokémon certain moves, providing they have the ability to learn them.
| Location | Move | Price |
| Toy Town | Giga Impact | 100000P |
| Toy Town | Random Move | Varies |
| 1-1 Trailhead Field - Battle Royale | Cut | Varies depending on Pokémon Strength |
| 1-2 Seabreeze Trail - Meadow | Low Sweep | Varies depending on Pokémon Strength |
| 1-2 Seabreeze Trail - Battle Royale | Rock Smash | Varies depending on Pokémon Strength |
| 1-3 Echo Valley - Forest | Growl | Varies depending on Pokémon Strength |
| 1-3 Echo Valley - Battle Royale Grass | Vine Whip | Varies depending on Pokémon Strength |
| 1-3 Echo Valley - Battle Royale Fire | Ember | Varies depending on Pokémon Strength |
| 1-3 Echo Valley - Battle Royale Water | Water Gun | Varies depending on Pokémon Strength |
| 1-4 Challengers' Ground - Meadow | Tail Whip | Varies depending on Pokémon Strength |
| 1-4 Challengers' Ground - Tower | Echoed Voice | Varies depending on Pokémon Strength |
| 1-4 Challengers' Ground - Battle Royale | Work Up | Varies depending on Pokémon Strength |
| Easterly Town | Solarbeam | 300000P |
| Easterly Town | Random Move | Varies depending on Pokémon Strength |
| 2-1 Sun-Dappled Bank - Treetops | Ingrain | Varies depending on Pokémon Strength |
| 2-2 Misty Edgewater - Forest | PoisonPowder | Varies depending on Pokémon Strength |
| 2-2 Misty Edgewater - Hauntyard | Will-o-Wisp | Varies depending on Pokémon Strength |
| 2-2 Misty Edgewater - Battle Royale | Astonish | Varies depending on Pokémon Strength |
| 2-3 Soothing Shore - Treetops | U-Turn | Varies depending on Pokémon Strength |
| 2-3 Soothing Shore - Battle Royale | Struggle Bug | Varies depending on Pokémon Strength |
| 2-4 Shimmering Lake - Treetops | Growth | Varies depending on Pokémon Strength |
| 2-4 Shimmering Lake - Cave | Harden | Varies depending on Pokémon Strength |
| 2-4 Shimmering Lake - Battle Royale | Round | Varies depending on Pokémon Strength |
| Westerly Town | Random Move | Varies depending on Pokémon Strength |
| Westerly Town | Random Move | Varies depending on Pokémon Strength |
| Westerly Town | Fire Blast | 30000P |
| Westerly Town | Move Swap | 15000P |
| 3-1 Rugged Flats - Canyon | Smack Down | Varies depending on Pokémon Strength |
| 3-1 Rugged Flats - Cave | Fury Swipes | Varies depending on Pokémon Strength |
| 3-1 Rugged Flats - Battle Royale | Facade | Varies depending on Pokémon Strength |
| 3-2 Volcanic Slope - Magma | Incinerate | Varies depending on Pokémon Strength |
| 3-2 Volcanic Slope - Battle Royale | Canyon Slide | Varies depending on Pokémon Strength |
| 3-3 Firebreathing Mountain - Factory | Volt Switch | Varies depending on Pokémon Strength |
| 3-3 Firebreathing Mountain - Tower | Sonicboom | Varies depending on Pokémon Strength |
| 3-3 Firebreathing Mountain - Battle Royale | Bulk Up | Varies depending on Pokémon Strength |
| Northerly Town | Random Move | Varies depending on Pokémon Strength |
| Northerly Town | Surf | 300000P |
| Northerly Town | Move Swap | 15000P |
| 4-2 Everspring Valley - Forest | Absorb | Varies depending on Pokémon Strength |
| 4-2 Everspring Valley - Meadow | Fling | Varies depending on Pokémon Strength |
| 4-2 Everspring Valley - Screw Shrine | Poison Jab | Varies depending on Pokémon Strength |
| 4-2 Everspring Valley - Screw Shrine | Pluck | Varies depending on Pokémon Strength |
| 4-3 Sunny Seashore - Canyon | Acrobatics | Varies depending on Pokémon Strength |
| 4-3 Sunny Seashore - Beach | Whirlpool | Varies depending on Pokémon Strength |
| 4-3 Sunny Seashore - Magma | Fire Spin | Varies depending on Pokémon Strength |
| 4-3 Sunny Seashore - Screw Shrine | Bulldoze | Varies depending on Pokémon Strength |
| 4-3 Sunny Seashore - Screw Shrine | Brick Break | Varies depending on Pokémon Strength |
| Axle Town | Random Move | Varies depending on Pokémon Strength |
| Axle Town | Random Move | Varies depending on Pokémon Strength |
| Axle Town | Move Swap | 15000P |
| Axle Town | Surf | 300000P |
| Axle Town | Any Move in Learnset | Varies (Exchange toys instead of coins) |
| World Axle B2F - Battle Royale | Return | Varies depending on Pokémon Strength |