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| As Pokémon Masters EX started and continued on, there has been a Main Story. Initially this just dealt with the welcome to Pasio with the Pokémon Masters League but has since branched out to include more story arcs. |  |
List of Story Arcs
| Icon | Arc Name | Release Data | Description |
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PML Arc | August 29th 2019 - July 30th 2021 | Team up with other Sync Pairs and take on the Pokémon Masters League |
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Villain Arc | September 30th 2021 - ??? | What plots are these villainous organisations hatching on Pasio now that the PML is over |
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Legendary Adventures | November 24th 2021 - ??? | A collection of stories in which you can team up with sync pairs that have Legendary Pokémon |