Trial Captain: Ilima
Location: Hau'oli City
Specialty: Normal-type

Details:
Ilima is actually a Trial Captain that you battle twice. First time you battle him, it will be for him to see if you are ready for his trial. His Smeargle has a different move depending upon which Starter Pokémon you picked.

Captain Ilima	Yungoos	Smeargle
Battle Type Items	Level 9	Level 10
	Attacks: Tackle Pursuit Leer	Attacks: Ember Tackle
	Hold Item: No Item	Hold Item: No Item
Rowlet Chosen

Captain Ilima	Yungoos	Smeargle
Battle Type Items	Level 9	Level 10
	Attacks: Tackle Pursuit Leer	Attacks: Water Gun Tackle
	Hold Item: No Item	Hold Item: No Item
Litten Chosen

Captain Ilima	Yungoos	Smeargle
Battle Type Items	Level 9	Level 10
	Attacks: Tackle Pursuit Leer	Attacks: Leafage Tackle
	Hold Item: No Item	Hold Item: No Item
Popplio Chosen

Trial Captain: Ilima
Location: Hau'oli City
Specialty: Normal-type

Details:
The second time you battle Ilima is slightly after the completion of the trial. Go to his house in the Hau'oli City and he will welcome you into his room and mention how he has been working on a new battling strategy and asks if you will join him in a battle. If you accept, he'll take you to the Trainer School for the battle.

Captain Ilima	Gumshoos	Smeargle
Battle Type Items	Level 15	Level 14
	Attacks: Tackle Pursuit Leer	Attacks: Quick Attack Ember Water Gun Leafage
	Hold Item: Normalium Z	Hold Item: No Item

Trial Captain: Lana
Location: Konikoni City
Specialty: Water-type

Details:
After defeating her trial, if you go to her house in Konikoni City and go to the back room. In there, you will find Lana's sisters who ask for you to play with them. Defeat them in battle and Lana will come in. Her sisters will ask for you to battle her in order to show who is the strongest trainer.

Captain Lana	Chinchou	Shellder	Araquanid
Battle Type Items	Level 26	Level 26	Level 27
	Attacks: Electro Ball Bubble Beam Thunder Wave	Attacks: Supersonic Icicle Spear Water Gun	Attacks: Bubble Beam Bug Bite Bite
	Hold Item: No Item	Hold Item: No Item	Hold Item: Waterium Z

Trial Captain: Kiawe
Location: Paniola Town, Royal Avenue - Sun Only
Specialty: Fire-type

Details:
At night, after you have beaten the Akala Grand Trial, you can go to Kiawe's house in Paniola Town. Go upstairs and you will find Kiawe in his room doing some training for his fire dancing. He says that he has to practice in it, like Pokémon battles and the note that the time has passed and he needs to go to the Thrifty Megamart. Follow him there and you will see him get let go from his job and his ex-boss hoping his dreams come true one day. Kiawe then spots you and challenges you in order to lift his spirits.

Captain Kiawe	Growlithe	Fletchinder	Marowak
Battle Type Items	Level 26	Level 26	Level 27
	Attacks: Bite Fire Fang	Attacks: Ember Quick Attack Peck	Attacks: Flame Wheel Hex Bonemerang Will-O-Wisp
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item

Trial Captain: Mallow
Location: Konikoni City - Lush Jungle - Moon Only
Specialty: Grass-type

Details:
In the day in Moon, after you have beaten the Akala Grand Trial, go to Mallow's room in the top floor of the restaurant in Konikoni City. She will ask you why you're there and the responses are to battle. She will suggest going to Lush Jungle for a teasure hunt. She says to look for the Wimpod and then she'll battle you. After that, her brother will mention that he needed her to do some shopping for him, but asks you to tell her to bring Wimpod home. Meet her in Lush Jungle and she'll battle you

Captain Mallow	Phantump	Shiinotic	Steenee
Battle Type Items	Level 26	Level 26	Level 27
	Attacks: Leech Seed Feint Attack Confuse Ray Astonish	Attacks: Ingrain Mega Drain Sleep Powder Astonish	Attacks: Teeter Dance Magical Leaf Double Slap Rapid Spin
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item

Trial Captain: Sophocles
Location: Pokémon League
Specialty: Electric-type

Details:
Sophocles, when you complete his trial, says right away that he wants to battle you. However, this will require a lot of waiting as the only time you can battle Sophocles is when he comes as a challenger to your position as Champion of the Pokémon League.

Captain Sophocles	Togedemaru	Magnezone	Electivire	Vikavolt	Golem
Battle Type Items	Level 61	Level 61	Level 61	Level 61	Level 61
	Attacks: Electric Terrain Zing Zap Spiky Shield Fell Stinger	Attacks: Flash Cannon Discharge Tri Attack Reflect	Attacks: Thunder Punch Giga Impact Fire Punch Quick Attack	Attacks: Bug Buzz Thunderbolt Air Slash Guillotine	Attacks: Stone Edge Steamroller Thunder Punch Heavy Slam
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item

Trial Captain: Acerola
Location: Pokémon League
Specialty: Ghost-type

Details:
The sixth Trial Captain is one that you will definitely battle through your play. Acerola becomes a member of the Elite Four and so has got multiple instances of battle against her.

Elite Four Acerola	Sableye	Drifblim	Dhelmise	Froslass	Palossand
Battle Type Items	Level 54	Level 54	Level 54	Level 54	Level 55
	Attacks: Shadow Claw Zen Headbutt Confuse Ray Fake Out	Attacks: Ominous Wind Focus Energy Amnesia Baton Pass	Attacks: Slam Shadow Ball Energy Ball Whirlpool	Attacks: Blizzard Shadow Ball Confuse Ray Ice Shard	Attacks: Shadow Ball Earth Power Giga Drain Iron Defense
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: Ghostium Z

Elite Four Acerola	Sableye	Drifblim	Dhelmise	Froslass	Palossand
Battle Type Items	Level 63	Level 63	Level 63	Level 63	Level 63
	Attacks: Shadow Claw Zen Headbutt Brick Break Fake Out	Attacks: Shadow Ball Thunderbolt Psychic Will-O-Wisp	Attacks: Phantom Force Heavy Slam Earthquake Brutal Swing	Attacks: Blizzard Shadow Ball Thunderbolt Ice Shard	Attacks: Shadow Ball Earth Power Sludge Bomb Giga Drain
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: Ghostium Z

Trial Captain: Mina
Location: Route 8
Specialty: Fairy-type

Details:
You don't actually meet Mina until you're about to do the final trial, which she has nothing to do with. She instead decides to create a trial, but you don't see it. You first battle her during the Ultra Beast story line where she brings information to Looker and Anabel and battles you to make sure the information is safe.

Captain Mina	Klefki	Granbull	Shiinotic	Wigglytuff	Ribombee
Battle Type Items	Level 61	Level 61	Level 61	Level 61	Level 61
	Attacks: Dazzling Gleam Flash Cannon Light Screen Reflect	Attacks: Crunch Play Rough Earthquake Stone Edge	Attacks: Spore Moonblast Dream Eater Giga Drain	Attacks: Dazzling Gleam Hyper Voice Flamethrower Ice Beam	Attacks: Pollen Puff Dazzling Gleam Psychic Energy Ball
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item

Trial Captain: Mina
Location: Poni Gauntlet
Specialty: Fairy-type

Details:
You can face Mina for a second time in Poni Gauntlet. After requesting you defeat all the trainers as part of her faux-trial, she will finally battle you again herself, with a similar team to before. She will give you a Bottle Cap for defeating her.

Captain Mina	Klefki	Granbull	Shiinotic	Wigglytuff	Ribombee
Battle Type Items	Level 61	Level 61	Level 61	Level 61	Level 61
	Attacks: Dazzling Gleam Flash Cannon Light Screen Reflect	Attacks: Crunch Play Rough Earthquake Stone Edge	Attacks: Spore Moonblast Dream Eater Giga Drain	Attacks: Dazzling Gleam Hyper Voice Flamethrower Ice Beam	Attacks: Pollen Puff Dazzling Gleam Psychic Energy Ball
	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: No Item	Hold Item: Fairium Z