Attack Name	Battle Type	Contest Type
Substitute
Power Points	Base Power	Accuracy
10	0	0
Battle Effect: Creates a decoy using 1/4 of the user's maximum HP.
Secondary Effect: Creates a decoy using 1/4 of the user's maximum HP.		Effect Rate: -- %
TM #	Appeal Points	Jam Points
None
Contest Effect: Can avoid being startled by others once.
BrightPowder	King's Rock	Physical Contact
No	No	No
Battle Palace Style	Battle Arena	Pokémon Hit in Battle
Defense	+0	User
Picture Example of Substitute

Pokémon That Learn Substitute By Level Up in Ruby/Sapphire/Emerald/Colosseum/XD:

No.	Pic	Name	Type 1	Type 2
#122		Mr. Mime
#352		Kecleon

Pokémon That Learn Substitute By Level Up in Fire Red/Leaf Green:

No.	Pic	Name	Type 1	Type 2
#122		Mr. Mime
#352		Kecleon

Pokémon That Learn Substitute By Move Tutor

No.	Pic	Name	Type 1	Type 2
#001		Bulbasaur
#002		Ivysaur
#003		Venusaur
#004		Charmander
#005		Charmeleon
#006		Charizard
#007		Squirtle
#008		Wartortle
#009		Blastoise
#012		Butterfree
#015		Beedrill
#016		Pidgey
#017		Pidgeotto
#018		Pidgeot
#019		Rattata
#020		Raticate
#021		Spearow
#022		Fearow
#023		Ekans
#024		Arbok
#025		Pikachu
#026		Raichu
#027		Sandshrew
#028		Sandslash
#029		Nidoran (F)
#030		Nidorina
#031		Nidoqueen
#032		Nidoran (M)
#033		Nidorino
#034		Nidoking
#035		Clefairy
#036		Clefable
#037		Vulpix
#038		Ninetales
#039		Jigglypuff
#040		Wigglytuff
#041		Zubat
#042		Golbat
#043		Oddish
#044		Gloom
#045		Vileplume
#046		Paras
#047		Parasect
#048		Venonat
#049		Venomoth
#050		Diglett
#051		Dugtrio
#052		Meowth
#053		Persian
#054		Psyduck
#055		Golduck
#056		Mankey
#057		Primeape
#058		Growlithe
#059		Arcanine
#060		Poliwag
#061		Poliwhirl
#062		Poliwrath
#063		Abra
#064		Kadabra
#065		Alakazam
#066		Machop
#067		Machoke
#068		Machamp
#069		Bellsprout
#070		Weepinbell
#071		Victreebel
#072		Tentacool
#073		Tentacruel
#074		Geodude
#075		Graveler
#076		Golem
#077		Ponyta
#078		Rapidash
#079		Slowpoke
#080		Slowbro
#081		Magnemite
#082		Magneton
#083		Farfetch'd
#084		Doduo
#085		Dodrio
#086		Seel
#087		Dewgong
#088		Grimer
#089		Muk
#090		Shellder
#091		Cloyster
#092		Gastly
#093		Haunter
#094		Gengar
#095		Onix
#096		Drowzee
#097		Hypno
#098		Krabby
#099		Kingler
#100		Voltorb
#101		Electrode
#102		Exeggcute
#103		Exeggutor
#104		Cubone
#105		Marowak
#106		Hitmonlee
#107		Hitmonchan
#108		Lickitung
#109		Koffing
#110		Weezing
#111		Rhyhorn
#112		Rhydon
#113		Chansey
#114		Tangela
#115		Kangaskhan
#116		Horsea
#117		Seadra
#118		Goldeen
#119		Seaking
#120		Staryu
#121		Starmie
#122		Mr. Mime
#123		Scyther
#124		Jynx
#125		Electabuzz
#126		Magmar
#127		Pinsir
#128		Tauros
#130		Gyarados
#131		Lapras
#133		Eevee
#134		Vaporeon
#135		Jolteon
#136		Flareon
#137		Porygon
#138		Omanyte
#139		Omastar
#140		Kabuto
#141		Kabutops
#142		Aerodactyl
#143		Snorlax
#144		Articuno
#145		Zapdos
#146		Moltres
#147		Dratini
#148		Dragonair
#149		Dragonite
#150		Mewtwo
#151		Mew
#152		Chikorita
#153		Bayleef
#154		Meganium
#155		Cyndaquil
#156		Quilava
#157		Typhlosion
#158		Totodile
#159		Croconaw
#160		Feraligatr
#161		Sentret
#162		Furret
#163		Hoothoot
#164		Noctowl
#165		Ledyba
#166		Ledian
#167		Spinarak
#168		Ariados
#169		Crobat
#170		Chinchou
#171		Lanturn
#172		Pichu
#173		Cleffa
#174		Igglybuff
#175		Togepi
#176		Togetic
#177		Natu
#178		Xatu
#179		Mareep
#180		Flaaffy
#181		Ampharos
#182		Bellossom
#183		Marill
#184		Azumarill
#185		Sudowoodo
#186		Politoed
#187		Hoppip
#188		Skiploom
#189		Jumpluff
#190		Aipom
#191		Sunkern
#192		Sunflora
#193		Yanma
#194		Wooper
#195		Quagsire
#196		Espeon
#197		Umbreon
#198		Murkrow
#199		Slowking
#200		Misdreavus
#203		Girafarig
#204		Pineco
#205		Forretress
#206		Dunsparce
#207		Gligar
#208		Steelix
#209		Snubbull
#210		Granbull
#211		Qwilfish
#212		Scizor
#213		Shuckle
#214		Heracross
#215		Sneasel
#216		Teddiursa
#217		Ursaring
#218		Slugma
#219		Magcargo
#220		Swinub
#221		Piloswine
#222		Corsola
#223		Remoraid
#224		Octillery
#225		Delibird
#226		Mantine
#227		Skarmory
#228		Houndour
#229		Houndoom
#230		Kingdra
#231		Phanpy
#232		Donphan
#233		Porygon2
#234		Stantler
#236		Tyrogue
#237		Hitmontop
#238		Smoochum
#239		Elekid
#240		Magby
#241		Miltank
#242		Blissey
#243		Raikou
#244		Entei
#245		Suicune
#246		Larvitar
#247		Pupitar
#248		Tyranitar
#249		Lugia
#250		Ho-oh
#251		Celebi
#252		Treecko
#253		Grovyle
#254		Sceptile
#255		Torchic
#256		Combusken
#257		Blaziken
#258		Mudkip
#259		Marshtomp
#260		Swampert
#261		Poochyena
#262		Mightyena
#263		Zigzagoon
#264		Linoone
#267		Beautifly
#269		Dustox
#270		Lotad
#271		Lombre
#272		Ludicolo
#273		Seedot
#274		Nuzleaf
#275		Shiftry
#276		Taillow
#277		Swellow
#278		Wingull
#279		Pelipper
#280		Ralts
#281		Kirlia
#282		Gardevoir
#283		Surskit
#284		Masquerain
#285		Shroomish
#286		Breloom
#287		Slakoth
#288		Vigoroth
#289		Slaking
#290		Nincada
#291		Ninjask
#292		Shedinja
#293		Whismur
#294		Loudred
#295		Exploud
#296		Makuhita
#297		Hariyama
#298		Azurill
#299		Nosepass
#300		Skitty
#301		Delcatty
#302		Sableye
#303		Mawile
#304		Aron
#305		Lairon
#306		Aggron
#307		Meditite
#308		Medicham
#309		Electrike
#310		Manectric
#311		Plusle
#312		Minun
#313		Volbeat
#314		Illumise
#315		Roselia
#316		Gulpin
#317		Swalot
#318		Carvanha
#319		Sharpedo
#320		Wailmer
#321		Wailord
#322		Numel
#323		Camerupt
#324		Torkoal
#325		Spoink
#326		Grumpig
#327		Spinda
#328		Trapinch
#329		Vibrava
#330		Flygon
#331		Cacnea
#332		Cacturne
#333		Swablu
#334		Altaria
#335		Zangoose
#336		Seviper
#337		Lunatone
#338		Solrock
#339		Barboach
#340		Whiscash
#341		Corphish
#342		Crawdaunt
#343		Baltoy
#344		Claydol
#345		Lileep
#346		Cradily
#347		Anorith
#348		Armaldo
#349		Feebas
#350		Milotic
#351		Castform
#352		Kecleon
#353		Shuppet
#354		Banette
#355		Duskull
#356		Dusclops
#357		Tropius
#358		Chimecho
#359		Absol
#361		Snorunt
#362		Glalie
#363		Spheal
#364		Sealeo
#365		Walrein
#366		Clamperl
#367		Huntail
#368		Gorebyss
#369		Relicanth
#370		Luvdisc
#371		Bagon
#372		Shelgon
#373		Salamence
#375		Metang
#376		Metagross
#377		Regirock
#378		Regice
#379		Registeel
#380		Latias
#381		Latios
#382		Kyogre
#383		Groudon
#384		Rayquaza
#385		Jirachi
#386		Deoxys

Pokémon That Learn Substitute By Breeding:

No.	Pic	Name	Type 1	Type 2
#035		Clefairy
#036		Clefable
#108		Lickitung
#113		Chansey
#115		Kangaskhan
#131		Lapras
#143		Snorlax
#161		Sentret
#162		Furret
#173		Cleffa
#175		Togepi
#176		Togetic
#183		Marill
#184		Azumarill
#242		Blissey
#263		Zigzagoon
#264		Linoone
#300		Skitty
#301		Delcatty
#311		Plusle
#312		Minun
#325		Spoink
#326		Grumpig
#359		Absol

Pokémon That Learn Substitute By Purifying or A Special Way: